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Room Temperature Baroplastic Processing of PS/PBA Nano-Blends
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  • Room Temperature Baroplastic Processing of PS/PBA Nano-Blends
  • Room Temperature Baroplastic Processing of PS/PBA Nano-Blends
저자명
Lee. Kwang-Hee,Ryu. Sang-Woog
간행물명
Macromolecular research
권/호정보
2012년|20권 12호|pp.1294-1299 (6 pages)
발행정보
한국고분자학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Room temperature baroplastic processing of polystyrene (PS) and poly(n-butyl acrylate) (PBA) was investigated through the formation of nanoblends of their polymer nanoparticles. Instead of core-shell or block copolymer structures, PS and PBA nanoparticles were synthesized separately through aqueous emulsion polymerization and then mixed and precipitated. The resulting nano-blends provided semi-transparent molding at $25^{circ}C$ under applied pressure, resembling that of core-shell and block copolymer baroplastic systems. Differential scanning calorimetry measurements of the compressed samples revealed the presence of intermixing glass transition between the two components, which indicated baroplastic processing. However, PS/poly(lauryl methacrylate) blends exhibited no intermixing glass transition, indicating no pressure-induced miscibility between the two phases.