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The Characterization of Polyacrylonitrile Fibers Stabilized by Electron Beam Irradiation
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  • The Characterization of Polyacrylonitrile Fibers Stabilized by Electron Beam Irradiation
  • The Characterization of Polyacrylonitrile Fibers Stabilized by Electron Beam Irradiation
저자명
Shin. Hye Kyoung,Jeun. Joon Pyo,Kang. Phil Hyun
간행물명
Fibers and polymers
권/호정보
2012년|13권 6호|pp.724-728 (5 pages)
발행정보
한국섬유공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This study investigates polyacrylonitile(PAN) fibers stabilized with various doses of electron beam irradiation (EBI) ability to produce carbon fibers. Feasibility was verified by FT-IR, the percent of gel fraction, density, DSC, XRD, and mechanical measurements. FT-IR spectra showed that the intensities of the stretching $C{equiv}N$ bonds decreased at 2,244 $cm^{-1}$ with increasing EBI dose. This de crease was related to cyclization of nitrile groups during EBI- stabilization. The degree of cyclization was determined from the gel fraction and density tests. The gel content and density of PAN fibers stabilized by EBI increased with an increase in the EBI dose. Thermal properties were characterized by differential scanning calorimetry (DSC) and thermally activated reactions. DSC curves showed that EBI treatment influenced the quantity of released heat and the exothermic position at low temperature over a wide temperature range. The strongest diffraction peak from the PAN precursor fiber arose from the (100) plane; its stabilization index (SI) was evaluated by X-ray diffraction. The X-ray results showed that the peak intensity decreases gradually with increasing EBI dose. In addition, tensile strength decreased the EBI stabilization level.