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The Solvent Effects on the Formation of Polyynes by Laser Ablation
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  • The Solvent Effects on the Formation of Polyynes by Laser Ablation
  • The Solvent Effects on the Formation of Polyynes by Laser Ablation
저자명
Park. Young-Eun,Shin. Seung-Keun,Park. Seung-Min
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2012년|33권 7호|pp.2439-2442 (4 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

In order to explore the effects of the solvent on the formation rate of polyynes, we investigated the absorption spectra of polyynes obtained by laser ablation of a graphite target in different solvents at 1064 nm. Polyynes so produced were confirmed by the Raman band around $2200cm^{-1}$ which corresponds to the carbon triple bonds. The production of polyynes by laser ablation turned out to be significantly affected by the ratio of the hydrogen and carbon atoms in the solvent molecule. No clear correlations were observed in the formation of polyynes for other properties of the solvent such bond dissociation energy, thermal conductivity, and total mass of hydrogen atoms per volume of solvent.