In this paper, we propose a SPN 256 bit block cipher so called XSB(eXtended SPN Block cipher) which has a symmetric structure in encryption and decryption. The proposed XSB is composed of the even numbers of N rounds where the first half of them, 1 to N/2-1 round, applies a pre-function and the last half of them, N/2+1 to N round, employs a post-function. Each round consists of a round key addition layer, a substiution layer, a byte exchange layer and a diffusion layer. And a symmetry layer is located in between the pre-function layer and the post-function layer. The symmetric layer is composed with a multiple simple bit slice involution S-Boxes. The bit slice involution S-Box symmetric layer increases difficult to attack cipher by Square attack, Boomerang attack, Impossible differentials cryptanalysis etc.