Most national critical key infrastructure, such like electricity, nuclear power plant, and petroleum is run on SCADA (Supervisory Control And Data Acquisition) system as the closed network type. These systems have treated the open protocols like TCP/IP, and the commercial operating system, which due to gradually increasing dependence on IT(Information Technology) is a trend. Recently, concerns have been raised about the possibility of these facilities being attacked by cyber terrorists, hacking, or viruses. In this paper, the method to minimize threats and vulnerabilities is proposed, with the virtual honeynet system architecture and the attack detection algorithm, which can detect the unknown attack patterns of Zero-Day Attack are reviewed.