The aim of this work was to investigate the combustion and nanoparticle emission characteristics of premixed charge compression ignition (PCCI) combustion at various test conditions using a single cylinder common-rail diesel engine. In order to create the homogeneity of fuel-air mixture, the premixed fuel (gasoline) was injected into premixing chamber during the intake process and then the diesel fuel was directly injected into the combustion chamber as an ignition source for the gasoline premixture. From these results, it revealed that the ignition delays and combustion durations were gradually prolonged and the peak combustion pressure were increased because diesel fuel was injected early injection timing with the increase of premixed ratio. In addition, as the increase of premixed ratio, total particle number is generally decreased and particle volume also indicated low levels at the direct injection timing from BTDC $20^{circ}$ to TDC. At further advanced injection timing, total particle number and volume were generally increased