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Preparation and Characterizations of C60/Polystyrene Composite Particle Containing Pristine C60 Clusters
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  • Preparation and Characterizations of C60/Polystyrene Composite Particle Containing Pristine C60 Clusters
  • Preparation and Characterizations of C60/Polystyrene Composite Particle Containing Pristine C60 Clusters
저자명
Kim. Jung-Woon,Kim. Kun-Ji,Park. Soo-Yeon,Jeong. Kwang-Un,Lee. Myong-Hoon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2012년|33권 9호|pp.2966-2970 (5 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Fullerene/polystyrene ($C_{60}$/PS) nano particle was prepared by using emulsion polymerization. Styrene and fullerene were emulsified in aqueous media in the presence of poly(N-vinyl pyridine) as an emulsion stabilizer, and polymerization was initiated by water soluble radical initiator, potassium persulfate. The obtained nano particles have an average diameter in the range of 400-500 nm. The fullerene contents in the nano particle can be controlled up to 15 wt % by varying the feed ratio, which was confirmed by themogravimetric analysis (TGA) and elemental analysis (EA). The structure and morphologies of the $C_{60}$/PS nano particles were examined by various analytical techniques such as dynamic light scattering (DLS), scanning electron microscope (SEM), transmission electron microscope (TEM), electron diffraction (ED) pattern, X-ray powder diffraction (XRD), and UV spectroscopy. Unlike conventional $C_{60}$/PS particles initiated by organic free radical initiators, in which the fullerene is copolymerized forming a covalent bond with styrene monomer, the prepared $C_{60}$/PS nano particles contain pristine fullerene as secondary particles homogeneously distributed in the polystyrene matrix.