This technical paper describes the analysis results of telemetry data for the initial activation of star trackers for an agile high accuracy low earth orbit satellite. The satellite was recently launched and is in the Launch and Early Operation Phases. It uses two SED36 star trackers manufactured by SODERN. The star tracker is separated by three parts, an optical head, an electronics box, and a baffle with maintaining optical head base plate temperature 20 degC in order to achieve the better performance in low frequency error. This paper presents the initial activation status, requirements and performance, anomaly occurrence, and noise equivalent angle performance analysis during the mission mode by processing the telemetry data.