In this paper, numerical analysis was performed about whether the flash fire of loaded shells breaks out in the virtual combat vehicle according to sorts of the kinetic energy ammunition as the preceding research for vulnerability analysis inside the combat system by an external threaty ammunition. In this simulation, Autodyn program was used and the Lee-Tarver ignition and growth model was used to determine the flash fire outbreak. In this study, the kinetic energy ammunition was set of type A and type B in two kinds and the loaded shells was set of COMPB, TNT, PBX9404 and ANB. As a result, TNT and PBX9404 have much higher flash fire probability than COMPB in high explosive, ANB has very low flash fire probability.