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Model Prediction and Experiments for the Electrode Design Optimization of LiFePO4/Graphite Electrodes in High Capacity Lithium-ion Batteries
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  • Model Prediction and Experiments for the Electrode Design Optimization of LiFePO4/Graphite Electrodes in High Capacity Lithium-ion Batteries
  • Model Prediction and Experiments for the Electrode Design Optimization of LiFePO4/Graphite Electrodes in High Capacity Lithium-ion Batteries
저자명
Yu. Seungho,Kim. Soo,Kim. Tae Young,Nam. Jin Hyun,Cho. Won Il
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2013년|34권 1호|pp.79-88 (10 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

$LiFePO_4$ is a promising active material (AM) suitable for use in high performance lithium-ion batteries used in automotive applications that require high current capabilities and a high degree of safety and reliability. In this study, an optimization of the electrode design parameters was performed to produce high capacity lithium-ion batteries based on $LiFePO_4$/graphite electrodes. The electrode thickness and porosity (AM density) are the two most important design parameters influencing the cell capacity. We quantified the effects of cathode thickness and porosity ($LiFePO_4$ electrode) on cell performance using a detailed one-dimensional electrochemical model. In addition, the effects of those parameters were experimentally studied through various coin cell tests. Based on the numerical and experimental results, the optimal ranges for the electrode thickness and porosity were determined to maximize the cell capacity of the $LiFePO_4$/graphite lithium-ion batteries.