Self-excited pulse jet is a specific nozzle with a closed chamber which can change a continuous jet into a pulse one. Energy of the pulse jet can be output not only unevenly but also with multifrequency. With the peak pressure of pulse jet, the hitting power would be 2~2.5 times higher than that of continuous jet. In order to reveal the correlation between the self-excited pulse frequency and nozzle diameter ratio, nozzle spacing and operating pressure, the model of 3D unsteady cavitation model has been used. We found that with the same nozzle structure parameters and the different operating pressure, the self-excited frequency and the width of peak crest are different, but the wave profiles are similar. With FFT, we also found that the less bandwidth of amplitude in low frequency range will lead to the wider wave crest of outlet velocity in its time domain, and the larger force of the strike will be gained. By studying the St of self-excite nozzle, not only the frequency of a certain nozzle can be predicted, but also a nozzle structure with a certain frequency can be designed.