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Synthesis and Characterization of Iridium-Containing Green Phosphorescent Polymers for PLEDs
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  • Synthesis and Characterization of Iridium-Containing Green Phosphorescent Polymers for PLEDs
  • Synthesis and Characterization of Iridium-Containing Green Phosphorescent Polymers for PLEDs
저자명
Xu. Fei,Kim. Hee Un,Mi. Dongbo,Lim. Jong Min,Hwang. Ju Hyun,Cho. Nam Sung,Lee. Jeong-Ik,Hwang. Do-Hoon
간행물명
Bulletin of the Korean Chemical Society
권/호정보
2013년|34권 2호|pp.399-405 (7 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

Two series of new green phosphorescent polymers bearing a bis(2-phenyl-pyridine)iridium(III)(dibenzoylmethane) [$(ppy)_2Irdbm$] complex were designed and synthesized. Poly-carbazole (PCbz) derivative or polyfluorene with pendant carbazole groups (PFCbz) were employed as host polymers for the iridium complex. The iridium complex monomer was copolymerized with the host monomers using varying monomer ratios via a Yamamoto coupling reaction. Efficient energy transfer from host to dopant unit was observed by increasing the ratio of the iridium guest in the copolymers. Electroluminescent devices with the configuration ITO/PEDOT:PSS/polymer/BmPyPB/LiF/Al were fabricated and characterized. The phosphorescent polymers composed of the iridium complex guest and polyfluorene with carbazole pendants as a host performed better than the polymers composed of the same guest and the main chain polycarbazole host. A maximum external quantum efficiency of 0.73%, a luminous efficiency of 1.21 cd/A, and a maximum luminance of 372 $cd/m^2$ were obtained from a device fabricated using one of the synthesized copolymers.