Missile and fighter aircraft have been challenged by low restoring nose-down pitching moment at high angle of attach. The consequence of weak nose-down pitching moment can be resulting in a deep stall condition. Especially, the pressure oscillation has a huge effect on noise generation, structure damage, aerodynamic performance and safety, because the flow has strong unsteadiness at high angle of attack. In this paper, the unsteady aerodynamics coefficients were analyzed at high angle of attack up to 50 degrees around two dimensional NACA0012 airfoil. The two dimensional unsteady compressible Navier-Stokes equation with a LES turbulent model was calculated by OHOC (Optimized High-Order Compact) scheme. The flow conditions are Mach number of 0.3 and Reynolds number of $10^5$. The lift, drag, pressure, entropy distribution, etc. are analyzed according to the angle of attack. The results of average lift coefficients are compared with other results according to the angle of attack. From a certain high angle of attack, the strong vortex formed by the leading edge are flowing downstream as like Karman vortex around a circular cylinder. The primary and secondary oscillating frequencies are analyzed by the effects of these unsteady aerodynamic characteristics.