Extractives of garlic (Allium scorodorpasum) and green pepper (Capsicum annuum L.) were used to prevent and exterminate rice weevils which contaminate stored rice. The extractives exhibited great efficacy against Sitophilus oryzae and Tribolium castaneum by annihilating all the weevils contained in a bottle. Furthermore, kraft paper coated by 5% extractives also displayed good effectiveness against the rice weevils. When rice weevils were stored with rice in a sack made of extractives-coated kraft paper, the number of living insects was sharply decreased according to elapsed time. In particular, 1,4-benzoquinone, which is very harmful to human, was detected from rice contaminated by Sitophilus oryzae and Tribolium castaneum through the analysis of GC/MS.