- 이온성 액체의 셀룰로오스 용해성 개선을 위한 전자빔 처리 효과
- ㆍ 저자명
- 이원실,정웅기,성용주,Lee. Won-Sil,Jung. Wong Gi,Sung. Yong Joo
- ㆍ 간행물명
- 펄프 종이기술
- ㆍ 권/호정보
- 2013년|45권 2호|pp.56-65 (10 pages)
- ㆍ 발행정보
- 한국펄프종이공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Electron beam treatment was applied for improving dissolution of cellulose with ionic liquids. Two ionic liquids, 1-allyl-3-methylimidazolium chloride ([Amim]Cl]: AC) and 1,3-dimethylimidazolium methylphosphite ([Dmim][$(MeO)(H)PO_2$]: Me) were used for this experiment. Treatment with electron beams up to dose of 400 kGy resulted in the increase of hot water extract and alkali extract of cotton pulp and the great reduction in the molecular weight of cellulose. For the dissolution of cotton pulp with two ionic liquids, the electron beam treated samples showed faster dissolution. The dissolved cellulose with Me ionic liquid were regenerated with acetonitrile and the structure of regenerated cellulose showed distinct difference depending on the electron beam treatment. Those results provide the electron beam pre-treatment could be applied as an energy efficient and environmentally benign method to increase the dissolution of cellulose with ionic liquids.