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Control of Working Temperature of Isothermal Magnetic Entropy Change in La0.8Nd0.2(Fe0.88Si0.12)13 by Hydrogen Absorption for Magnetic Refrigerants
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  • Control of Working Temperature of Isothermal Magnetic Entropy Change in La0.8Nd0.2(Fe0.88Si0.12)13 by Hydrogen Absorption for Magnetic Refrigerants
  • Control of Working Temperature of Isothermal Magnetic Entropy Change in La0.8Nd0.2(Fe0.88Si0.12)13 by Hydrogen Absorption for Magnetic Refrigerants
저자명
Fujieda. S.,Fujita. A.,Fukamichi. K.,Suzuki. S.
간행물명
Journal of magnetics
권/호정보
2013년|18권 2호|pp.150-154 (5 pages)
발행정보
한국자기학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

$La_{1-z}Nd_z(Fe_{0.88}Si_{0.12})_{13}$ and their hydrides were investigated to obtain large magnetocaloric effects (MCEs) in a wide temperature range, including room temperature, for applications in magnetic refrigents. Since the magnetization change due to the itinerant-electron metamagentic (IEM) transition for $La_{1-z}Nd_z(Fe_{0.88}Si_{0.12})_{13}$ becomes larger with increasing z, the isothermal magnetic entropy change ${Delta}S_m$ and the relative cooling power (RCP) are enhanced. In addition, the Curie temperatrue $T_C$ of $La_{0.8}Nd_{0.2}(Fe_{0.88}Si_{0.12})_{13}$ is increased from 193 to 319 K by hydrogen absorption, with the IEM transition. The maximum value of $-{Delta}S_m$, $-{Delta}S{_m}^{max}$, in a magnetic field change of 2 T for $La_{0.8}Nd_{0.2}(Fe_{0.88}Si_{0.12})_{13}H_{1.1}$ is about 23 J/kg K at $T_C$ = 288 K, which is larger than that of 19 J/kg K at $T_C$ = 276 K for $La(Fe_{0.88}Si_{0.12})_{13}H_{1.0}$. The value of RCP = 179 J/kg of the former is also larger than 160 J/kg of the latter. It is concluded that the partial substitution of Nd improves MCEs in a wide temperautre range, including room temperature.