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Graphene Nanoplatelets as a Solid Phase Extraction Sorbent for Analysis of Chlorophenols in Water
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  • Graphene Nanoplatelets as a Solid Phase Extraction Sorbent for Analysis of Chlorophenols in Water
  • Graphene Nanoplatelets as a Solid Phase Extraction Sorbent for Analysis of Chlorophenols in Water
저자명
Sadanala. Krishna Chaitanya,Chung. Bong Chul
간행물명
Journal of the Korean Society for Applied Biological Chemistry
권/호정보
2013년|56권 6호|pp.673-678 (6 pages)
발행정보
한국응용생명화학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Graphene nanoplatelets are a novel class of carbon nanostructures. They possess an ultra high surface area, and thus have great potentials for the use as sorbent materials. We herein demonstrate the use of graphene nanoplatelets as an adsorbent material for solid-phase extraction. Surface compositions of graphene nanoplatelets were examined by X-ray photoelectron spectroscopy. Scanning electron and transmission electron microscopies were performed to elucidate the morphology of graphene nanoplatelets. Three chlorophenols, 3-chlorophenol, 4-chlorophenol, and 2,4-dichlorophenols were selected as model analytes and extracted on a graphene nanoplatelets-packed solid-phase extraction cartridge, followed by elution with alkaline methanol. The extracted chlorophenols were identified and quantified by UV-vis spectrophotometer. Under the optimized experimental conditions, good linearity ($R^2$ >0.9969), recovery (95-103%), precision (<12%), and accuracy (< ${pm}9$%) were achieved. The advantages of graphene nanoplatelets as solid phase extraction adsorbent, such as good reusability and no impact of sorbent drying, have been detailed. The present study proposes a useful method for water sample pretreatment and reveals the potential of graphene nanoplatelets as an excellent sorbent material in analytical processes.