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Application of a Gas Chromatography/Luminol Detection System for Peroxyacetyl Nitrate Airborne Measurement
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  • Application of a Gas Chromatography/Luminol Detection System for Peroxyacetyl Nitrate Airborne Measurement
  • Application of a Gas Chromatography/Luminol Detection System for Peroxyacetyl Nitrate Airborne Measurement
저자명
Khang. Bumju,Ahn. Joon Young,Song. Dasol,Lee. Gangwoong
간행물명
Asian journal of atmospheric environment
권/호정보
2013년|7권 2호|pp.105-113 (9 pages)
발행정보
한국대기환경학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

We constructed and tested an airborne peroxyacetyl nitrate (PAN) monitoring system based on luminol chemiluminescence detection with fast gas chromatography. This system allowed for simultaneous measurement of PAN and nitrogen dioxide ($NO_2$) with a time resolution of <2 min. Actual sample masses within the fixed volume sample loop at various altitudes and temperatures were adjusted to standard atmosphere, using measured pressures and temperatures. The airborne PAN measurement system was evaluated during two field studies above the southern Korean Peninsula in August and October 2009. The detection limit based on the ISO approach was 0.035 ppbv PAN, well below the observed concentrations of 0.185-1.49 ppbv during these studies. Under these conditions, the PAN mixing ratios were positively correlated with $O_x$ ($O_x=O_3+NO_2$), with slopes varying between 0.014 and 0.033 and intercepts between 22.6 and 55.1 ppbv $O_x$. The intercepts corresponded roughly to background $O_x$ mixing ratios in central Europe; however, the slopes were above the range of slopes reported in other studies. We also enhanced the durability, safety, and ease of maintenance of the PAN monitoring system by redesigning the structure of the conventional luminol cell.