Recently, high-performance steels have been increasingly used for structural materials in buildings and bridges with the demand for high-rise and long-span of main structures. This paper offers a series of basic study for the design specification of structural members using high performance steel, that is material properties of HSA800 (High-performance rolled steel for building structures). Built-up square tube stub columns with variables of width-to-thickness ratios are planned as a parametric study in order to investigate the local buckling behaviors and check the current design limit of width-to-thickness ratio. In addition, the buckling behaviors of stub columns obtained finite element (FE) analysis were compared with those from experimental tests. The verified FE model was used for parametric study and checked applicability of high-strength steel on current design specification.