기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
Tetramethylthiuram monosulfide를 ionophore로 이용한 납 이온 선택성 poly(aniline) 고체 접촉 전극
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • Tetramethylthiuram monosulfide를 ionophore로 이용한 납 이온 선택성 poly(aniline) 고체 접촉 전극
  • Lead Ion Selective Solid Contact Electrode based on Tetramethylthiuram monosulfide ionophore
저자명
한원식,박운석,권혜영,이영훈,홍태기,Han. Won-Sik,Park. Woon-Suk,Kwon. Hye-Yeong,Lee. Young-Hoon,Hong. Tae-Kee
간행물명
한국유화학회지
권/호정보
2013년|30권 2호|pp.356-361 (6 pages)
발행정보
한국유화학회
파일정보
정기간행물|
PDF텍스트
주제분야
기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

Lead (II) ion selective poly(aniline) solid contact electrode based on Tetramethylthiuram monosulfide ionophore as a sulfur containing sensing material is successfully developed. The electrode exhibits good linear response of 25.6 mV / decade (at $20{pm}0.2^{circ}C$, r2=0.995) within the concentration range of $1.0{ imes}10^{-1}{sim}4.0{ imes}10^{-7}$ M Pb (II). The composition of this electrode was Ionophore : PVC : dioctylphthalate : potassiumtetrakis(4-chlorophenyl)borate : Oleic acid = 5.0 : 20.0 : 25.0 : 4.0 : 5.0. When we consider the results of using different composition electrodes based on only one potassiumtetrakis(4-chlorophenyl)borate or Oleic acid liphophlic additive, poly(aniline) solid contact electrode based on Tetramethylthiuram monosulfide ionophore with potassiumtetrakis(4-chlorophenyl)borate and Oleic acid liphophlic additive had the best result in response characteristics. The electrode shows good selectivity for lead (II) ion in comparison with alkali, alkaline earth, transition and heavy metal ions. This electrode is suitable for use with aqueous solutions of pH 3.0 ~ 7.0 and their standard deviation in the measured emf differences was ${pm}2.94$ mV at Tris buffered lead sample solution of $1.0{ imes}10^{-2}$ M and ${pm}2.82$ mV at Tris buffered lead sample solution of $1.0{ imes}10^{-3}$ M. Their stabilization time was less than 710 s. and response time was less than 16 s.