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흐름식 아임계수를 이용한 PAHs 오염토양 정화 영향인자
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  • 흐름식 아임계수를 이용한 PAHs 오염토양 정화 영향인자
저자명
조영태,박정훈,Jo. Young-Tae,Park. Jeong-Hun
간행물명
지하수토양환경
권/호정보
2013년|18권 4호|pp.1-7 (7 pages)
발행정보
한국지하수토양환경학회
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정기간행물|
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기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Subcritical water which acts as organic solvent with increasing temperature and pressure because dielectric constant and viscosity decrease can be used to remediate PAHs-contaminated soil. Factors influencing on extraction were studied with varying the water temperature $200{sim}275^{circ}C$, extraction time 0~90 min, flow rate 10~100 mL/min and pressure 3.9~10MPa. 300 g of soil sample which was contaminated with PAHs(naphthalene, phenanthrene, fluoranthene and pyrene; 423, 420, 539 and 428 mg/kg of initial concentration) was packed into the cell and placed to reactor and then the subcritical water was pumped through the cell for PAHs extraction. Naphthalene was removed almost 100% at relatively low temperature ($200^{circ}C$). The removal rate of phenanthrene, fluoranthene, and pyrene increased by 8, 26, and 23% when the temperature increased from 200 to $275^{circ}C$; and it was gradually increased as extraction time increased from 0 to 90 min. Decreasing removal rate when water flow rate increased from 10 to 30 mL/min, but there was no significant change after 30 mL/min. This is supposed due to channeling phenomenon. The pressure was not an effective factor for extraction of PAHs in this study. Based on the results, the importance of effective factor was in following sequence: temperature >> time > flow rate.