This paper proposes a validation model using a reverberation chamber for verification of the effectiveness and accuracy of the statistical power balance (PWB) method. The PWB method treats electromagnetic (EM) field distributions in certain environments as a representative value of an "ensemble" average, so a reverberation chamber is utilized as a testing apparatus to experimentally simulate the sets of measurement field "ensemble" inside a complex environment. Measurements are performed with various test conditions for environmental loss using flat absorbers, and front and side doors of the chamber. Comparison between the PWB analysis and the measurement results shows good agreement, indicating the usefulness of this statistical analysis method for stating the electromagnetic field inside the EM zone as a representative value to general structures.