This paper describes a DC-DC boost converter for thermoelectric energy harvesting. The designed converter boosts the VDD through a start-up block from a low-output voltage of a thermoelectric device and the boosted VDD is used to operate the internal control block. When the VDD reaches a predefined value, a detector circuit makes the start-up block turn off to minimize current consumption. The final boosted VOUT is achieved by alternately operating the DC-DC converter for VDD and the main DC-DC converter for VOUT according to the comparator outputs. Simulation results shows that the designed converter generates 2.65V from an input voltage of 200mV and its maximum power efficiency is 63%. The area of the chip designed using a 0.35um CMOS process is $1.3mm{ imes}0.7mm$ including pads.