In this study, we investigated the physical properties of powders made from agricultural byproducts, including rice straw, peanut husks, and garlic stems, to manufacture a new organic filler used for making paperboard. These materials were collected individually, and then we measured their chemical compositions. The byproducts were ground with a laboratory grinder and fractionated with 60-, 100-, and 200-mesh sieves to make many grades of organic fillers. After the grinding and fractionation, the yield, mean particle size, and particle size distribution of each grade were measured. Particle shapes were also investigated using a scanning electron microscope. The organic filler made from rice straw had the highest yield of the largest particle size group and higher contents of cellulose and hemicellulose than those made from peanut husks and garlic stems. The rice straw also showed more regular particle shapes and a lower aspect ratio than the other agricultural byproducts.