In this study, experiment and numerical analysis were conducted to identify the heat transfer characteristics and behavior of high-strength concrete upon a fire. The numerical analysis was employed to forecast the characteristics and properties of the high-strength concrete upon a fire, which can not be accomplished through a fire test due to the specific conditions and restrictions associated with the test. The result of the numerical analysis was compared with that of the test to verify the reliability of the analysis. In the numerical analysis of the heat transfer characteristics and behavior of 80 and 100 MPa high-strength concrete upon a fire, the commercial software of ABAQUS(V.6.8) was used. It was observed from the experiment that the contraction of the concrete with fiber-cocktail was mitigated by 25~55 % compared with that without fiber-cocktail because the fiber controlled the heat transfer of the concrete and thus improved the fire-resistance performance of the column.