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Hydrogen Permeation of SiC-CeO2 Composite Membrane by Dip-coating Process
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  • Hydrogen Permeation of SiC-CeO2 Composite Membrane by Dip-coating Process
  • Hydrogen Permeation of SiC-CeO2 Composite Membrane by Dip-coating Process
저자명
Park. Jihye,Jung. Miewon
간행물명
한국세라믹학회지
권/호정보
2013년|50권 6호|pp.485-488 (4 pages)
발행정보
한국세라믹학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

A SiC-$CeO_2$ composite membrane was successfully fabricated using an ally-hydridopolycarbosilane (AHPCS) binder and treated by dip-coating at 60 times with a $CeO_2$ sol solution. The dip-coated SiC membrane was calcined at 773 K and then sintered at 1173 K under an air atmosphere. The coated membrane was characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and a BET surface analysis. The difference in permeation performance between $H_2$ and CO gases was measured by varying the temperature. The permeation flux of $H_2$ on the SiC membrane with layered $CeO_2$ was obtained as $8.45{ imes}10^{-6};mol/m^2sPa$ at room temperature. The CO permeation flux was $2.64{ imes}10^{-6};mol/m^2sPa$ at room temperature. The reaction enthalpy (${Delta}H^{circ}$) for the hydrogen permeation process was calculated as -7.82 J/mol by Arrhenius plots.