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국내 토지이용도별 토양 중 다환방향족탄화수소류(PAHs)의 농도 수준 및 분포 특성
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  • 국내 토지이용도별 토양 중 다환방향족탄화수소류(PAHs)의 농도 수준 및 분포 특성
저자명
노회정,윤정기,윤대근,유순주,김태승,이재영,Noh. Hoe-Jung,Yoon. Jeong Ki,Yun. Dae-Geun,Yu. Soon-Ju,Kim. Tae Seung,Lee. Jai-Young
간행물명
지하수토양환경
권/호정보
2014년|19권 6호|pp.59-71 (13 pages)
발행정보
한국지하수토양환경학회
파일정보
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

We investigated soil contamination depending on the land use by examining the contamination levels and distribution characteristics of 16 polycyclic aromatic hydrocarbons (PAHs) in the national soil. Total PAHs (the sum of 16 PAH concentrations) and carcinogenic PAHs (the sum of seven carcinogenic PAH concentrations) were $8.50{sim}3,437.16{mu}g/kg$ and $2.94{sim}2,136.96{mu}g/kg$, respectively. The concentration of benzo(a)pyrene, one of the contaminants regulated by the soil quality standard in the nation, was $ND{sim}924.73{mu}g/kg$. Its maximum value of $924.73{mu}g/kg$ was detected in railroad (Region 3) and is approximately 13% of the standard value for Region 3 (i.e., 7 mg/kg). We also investigated the characteristics of contamination sources of PAHs in soil of the upland, forests, roads, and railroads, examining the fraction distribution of PAHs concentration by the number of benzene rings against the total PAHs concentration. The results demonstrate that the mean fraction of 4~6-ring PAHs against total PAHs concentration in soil was in the range of 51.8~80.7% with relative abundance of high-molecular PAHs, showing that the origin of contamination is under the category of combustion sources. When the molecular indices (Flu/(Flu/Pyr), Ant/(Ant+Phe), InP/(InP+BP), and BaA/(BaA+Chr)) were applied, they were also categorized as petroleum-based combustion sources. The individual PAH concentrations in soil by the land use were grouped into Regions 1, 2, and 3, which are statistically treated and are the parts of the national category system of soil quality standard. As a result, the concentration level of 16 PAHs was $0.02{sim}2.63{mu}g/kg$ in Region 1, $0.05{sim}4.26{mu}g/kg$ in Region 2, and $2.36{sim}178.27{mu}g/kg$ in Region 3. The concentration level of 6 carcinogenic PAHs was 14.2~320.4% against that of benzo(a)pyrene in Region 3 and sites of recycling waste sleepers. Considering that there were similarities among PAHs in terms of structures and toxicities, it would be recommended to review other types of carcinogenic PAHs together with benzo(a)pyrene when developing the soil quality standards in the nation.