Taking sample processes from the combined heat and power plant in Busan Fashion Color Industry Complex, the characteristics and amounts of greenhouse gas (GHGs) emissions were analysed and calculated, respectively. Based on the results, environmental assessment was evaluated for recent 3 years. The amounts of GHG emissions from 2011 to 2013 were estimated at 182,750, 184,384 and 190,250 $Ton.CO_2eq/year$, respectively. GHG emissions from stationary combustion sources were found to be more than 99 % of the total emissions. Also, the overall eco-efficiency indicator for environmental assessment was more than 1, suggesting that these results would be beneficial for GHG emissions allowance allocations.