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암모니움 디티오카바메이트계 이온성 액체의 합성 및 내마모성능 (I)
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  • 암모니움 디티오카바메이트계 이온성 액체의 합성 및 내마모성능 (I)
저자명
백승엽,김남균,신지훈,정근우,김영운,Baek. Seung-Yeob,Kim. Nam-Kyun,Shin. Jihoon,Chung. Keunwo,Kim. Young-Wun
간행물명
윤활학회지
권/호정보
2014년|30권 6호|pp.323-329 (7 pages)
발행정보
한국윤활학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The friction-reducing properties of lubricants containing ionic liquids based on ammonium dithiocarbamate are studied. The ionic liquids are produced through the following two steps: the synthesis of sodium alkyl dithiocarbamates via the substitution reaction of dialkylamine and carbon disulfide and their subsequent conversion into ammonium dithiocarbamate-based ionic liquids through an ion-exchange reaction with a quaternary alkyl ammonium halide salt. The structures of the ionic liquids are characterized by NMR spectroscopy and Fourier transform infrared spectroscopy. The isolated yields of the ionic liquids, which are viscous and pale yellow, are approximately 92%. The Brookfield viscosities and pour points of the ionic liquids are determined. Further, their wear resistances are measured through the four-ball wear test and the Schwingung Reibung Ver-schleiss (oscillation, friction, wear) test. The wear scar diameter of the lubricants containing 1 wt of the quaternary alkyl ammonium dithiocarbamate-based ionic liquids (0.475-0.631 mm) is significantly lower than that of the base oil (0.825 mm), proving that the ammonium dithiocarbamate-based ionic liquids have good friction-reducing characteristics. However, these friction-reducing characteristics fade significantly after long-term storage, owing to the degradation of the ionic liquids.