Krylov-Schur iteration method has been applied to the 2-Dim. waveguides of the varied geometrical structure. The eigen-equations for them have been constructed from FEM based on the tangential edge vectors of triangular elements. The eigen-values and their modes have been determined from the diagonal components of the Schur matrices and its transforming matrices. The eigen-pairs as the results have been revealed visually in the schematic representations.