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침전제의 종류 및 침전 공정의 변화가 β-Ga2O3 분말 합성에 미치는 영향
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  • 침전제의 종류 및 침전 공정의 변화가 β-Ga2O3 분말 합성에 미치는 영향
저자명
황수현,최영종,고정현,김태진,전덕일,조우석,한규성,Hwang. Su Hyun,Choi. Young Jong,Ko. Jeong Hyun,Kim. Tae Jin,Jeon. Deok Il,Cho. Woo Suk,Han. Kyu Sung
간행물명
한국재료학회지
권/호정보
2014년|24권 4호|pp.214-220 (7 pages)
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한국재료학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

In this research, a precipitation method was used to synthesize ${eta}-Ga_2O_3$ powders with various particle morphologies and sizes under varying precipitation conditions, such as gallium nitrate concentration, pH, and aging temperature, using ammonium hydroxide and ammonium carbonate as precipitants. The obtained powders were characterized in detail by XRD, SEM, FT-IR, and TG-DSC. From the TG-DSC result, GaOOH phase was transformed to ${eta}-Ga_2O_3$ at around $742^{circ}C$, and weight loss percent was about 14 % when $NH_4OH$ was used as a precipitant. Also, ${eta}-Ga_2O_3$ formed at $749^{circ}C$ and weight loss percent was about 15 % when $(NH)_2CO_3$ was used as a precipitant. XRD results showed that the obtained $Ga_2O_3$ had pure monoclinic phase in both cases. When $(NH)_2CO_3$ was used as a precipitant, the particle shape changed and became irregular. The range of particle size was about $500nm-4{mu}m$ based on various concentrations of gallium nitrate solution with $NH_4OH$. The particle size was increased from $1-2{mu}m$ to $3-4{mu}m$ and particle shape was changed from spherical to bar type by increasing aging temperature over $80^{circ}C$.