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Preparation and Gas Permeability of ZIF-7 Membranes Prepared via Two-step Crystallization Technique
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  • Preparation and Gas Permeability of ZIF-7 Membranes Prepared via Two-step Crystallization Technique
  • Preparation and Gas Permeability of ZIF-7 Membranes Prepared via Two-step Crystallization Technique
저자명
Li. Fang,Li. Qiming,Bao. Xinxia,Gui. Jianzhou,Yu. Xiaofei
간행물명
Korean chemical engineering research
권/호정보
2014년|52권 3호|pp.340-346 (7 pages)
발행정보
한국화학공학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Continuous and dense ZIF-7 membranes were successfully synthesized on ${alpha}-Al_2O_3$ porous substrate via two-step crystallization technique. ZIF-7 seeding layer was first deposited on porous ${alpha}-Al_2O_3$ substrate by in-situ low temperature crystallization, and then ZIF-7 membrane layer can be grown through the secondary high-temperature crystallization. Two synthesis solutions with different concentration were used to prepare ZIF-7 seeding layer and membrane layer on porous ${alpha}-Al_2O_3$ substrate, respectively. As a result, a continuous and defect-free ZIF-7 membrane layer can be prepared on porous ${alpha}-Al_2O_3$ substrate, as confirmed by scanning electron microscope. XRD characterization shows that the resulting membrane layer is composed of pure ZIF-7 phase without any impurity. A single gas permeation test of $H_2$, $O_2$, $CH_4$ or $CO_2$ was conducted based on our prepared ZIF-7 membrane. The ZIF-7 membrane exhibited excellent H2 molecular sieving properties due to its suitable pore aperture and defect-free membrane layer.