In order to investigate the characteristics of the gradient fluorinated polyacrylate and polyurethane latex blend films, the fluorinated polyacrylate emulsion and the polyurethane emulsion were synthesized, and then the both emulsions were blended at a series of ratios. The effects of content of the fluorinated polyacrylate on the gradient structure and surface property of the blended films were assessed by AFM, XPS, SEM-EDX and surface free energy measurements. It appeared that, while the content of the fluorinated polyacrylate latex was up to 30%, the fluorinated polyacrylate particles were selectively gathered on the film-air (F-A) and film-glass (F-G) interfaces at room temperature. When the content of the fluorinated polyacrylate was under 30%, the gradient structure of fluorinated component was not evident. The further increasing of fluorinated polyacrylate in the mixed system facilitated the formation and enlargement of gradient structure, but the adhesion of film decreased a little.