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Sonophotocatalytic Performance of Bi2Se3-Graphene/TiO2 Hybrid Nanomaterials Synthesized with a Microwave-assisted Method
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  • Sonophotocatalytic Performance of Bi2Se3-Graphene/TiO2 Hybrid Nanomaterials Synthesized with a Microwave-assisted Method
  • Sonophotocatalytic Performance of Bi2Se3-Graphene/TiO2 Hybrid Nanomaterials Synthesized with a Microwave-assisted Method
저자명
Zhu. Lei,Jo. Sun-Bok,Ye. Shu,Ullah. Kefayat,Oh. Won-Chun
간행물명
한국세라믹학회지
권/호정보
2014년|51권 3호|pp.162-169 (8 pages)
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한국세라믹학회
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정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This paper introduces a microwave-assisted synthesis method to prepare hybrid $Bi_2Se_3-GR/TiO_2$ nanocomposites, which exhibit superior properties over single component materials. The as-prepared composites were characterized by XRD, UV-vis absorbance spectra, SEM,TEM, EDX, and BET analyses, revealing uniform covering of the graphene nanosheet with $Bi_2Se_3$ and $TiO_2$ nanocrystals. For visible light photocatalysis of Rh.B, a significant enhancement in the reaction rate was consequently observed with $Bi_2Se_3-GR/TiO_2$ composites. The degradation rate($k_{app}$) obtained for sonophotocatalysis was $6.8{ imes}10^{-3}min^{-1}$, roughly 2.2 times better than that of VL photocatalysis under higher concentrations of Rh.B. The sonophotocatalysis was faster due to greater formation of reactive radicals as well as an increase of the active surface area of the $Bi_2Se_3-GR/TiO_2$ composites. The high activity is attributed to the synergetic effects of high charge mobility and red shift of the absorption edge of $Bi_2Se_3-GR/TiO_2$.