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Rheology and viscosity scaling of gelatin/1-allyl-3-methylimidazolium chloride solution
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  • Rheology and viscosity scaling of gelatin/1-allyl-3-methylimidazolium chloride solution
  • Rheology and viscosity scaling of gelatin/1-allyl-3-methylimidazolium chloride solution
저자명
Qiao. Congde,Li. Tianduo,Zhang. Ling,Yang. Xiaodeng,Xu. Jing
간행물명
Korea-Australia rheology journal
권/호정보
2014년|26권 2호|pp.169-175 (7 pages)
발행정보
한국유변학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Gelatin/1-allyl-3-methylimidazolium chloride solutions are prepared by using the ionic liquid 1-allyl-3-methylimidazolium chloride as solvent. The rheological properties of the gelatin solutions have been investigated by steady shear and oscillatory shear measurements. In the steady shear measurements, the gelatin solutions with high concentration show a shear-thinning flow behavior at high shear rates, while another shear thinning region can be found in the dilute gelatin solutions at low shear rates. The overlap concentration of gelatin in [amim]Cl is 1.0 wt% and the entanglement concentration is a factor of 4 larger (4.0 wt%). The high intrinsic viscosity (295 mL/g) indicates that the gelatin chains dispersed freely in the ionic liquid and no aggregation phenomenon occurs in dilute gelatin solution. The frequency dependences of modulus changed obviously with an increase in gelatin concentration. The empirical time-temperature superposition principle holds true at the experimental temperatures.