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석탄계 타르의 열처리 중 압력변화에 따른 변성 콜타르 핏치의 미세구조 및 물성 변화
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  • 석탄계 타르의 열처리 중 압력변화에 따른 변성 콜타르 핏치의 미세구조 및 물성 변화
저자명
고효준,정성모,한지훈,박창욱,김명수,임연수,Ko. Hyo Joon,Chung. Sung Mo,Han. Ji Hoon,Park. Chang Uk,Kim. Myung-Soo,Lim. Yun-Soo
간행물명
한국재료학회지
권/호정보
2014년|24권 6호|pp.293-300 (8 pages)
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한국재료학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Coal-tar pitch, a feedstock which can be heat-treated to create graphite, is composed of very complex molecules. Coal-tar pitch is a precursor of many useful carbon materials (e.g., graphite, carbon fibers, electrodes and matrices of carbon/carbon composites). Modified coal-tar pitch (MCTP) was prepared using two different heat-treatment methods and their properties were characterized and compared. One was prepared using heat treatment in nitrogen gas; the other was prepared under a pressure of 350 mmHg in air. The MCTPs were investigated to determine several properties, including softening point, C/H ratio, coke yield, formation of anisotropic mesophase and viscosity. The MCTPs were subject to considerable changes in chemical composition due to condensation and polymerization in the used-as-received coal-tar pitch after heat-treatment under different conditions. The MCTPs showed considerable increases in softening point, C/H ratio, and coke yield, compared to those of as-received coal-tar pitch. The MCTP formed by heat-treatment in nitrogen showed isotropic phases below $350^{circ}C$ for 1 h of soaking time. However, MCTP heat-treated under high pressure (350 mmHg) showed isotropic phases below $300^{circ}C$, and showed anisotropic phases above $350^{circ}C$, for 1 h of soaking time. The viscosity of the MCTPs increased with increase in their softening points.