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불화온실가스의 흡수단면적 측정을 통한 지구온난화지수의 추정
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  • 불화온실가스의 흡수단면적 측정을 통한 지구온난화지수의 추정
저자명
김지혜,이정순,Kim. Jihye,Lee. Jeongsoon
간행물명
한국대기환경학회지
권/호정보
2014년|30권 4호|pp.387-397 (11 pages)
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한국대기환경학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

This work aims at estimating global warming potentials (GWP) of $CF_3Br$ and HFC-134a among green house gases. It has been reported that they have much higher GWP than $CO_2$ in the atmosphere. $CF_3Br$, halon 1301 which is well known to be a fire extinguisher, as one of the bromine-containing halons has been banned since 2003 due to destruction of ozone. HFCs, a kind of chiller which replaced chlorofluorocarbons (CFCs) are one of greenhouse gases regulated by the Kyoto Protocol. In this study, we produced GWPs of $CF_3Br$ and HFC-134a by calculating a life time and measuring an absorption cross section to obtain a radiative forcing (RF). Their absorption cross sections were measured by using Fourier-transformed infrared spectroscopy (FTS) with a gas cell filled with their certified reference materials at room temperature. As a result, the RFs of $CF_3Br$ and HFC-134a were 0.32 and $0.168Wm^{-2}ppb^{-1}$, respectively and the GWPs were calculated as 7989, 6076, 3903 for $CF_3Br$ and 3855, 1300, 656 for HFC-134a for the time horizon of 20, 100, 500 years, respectively. Overall, uncertainty of the estimated GWPs can be estimated to be about 2.6%. Our results were compared with those proposed by the previous studies (IPCC, 2007; WMO, 1999).