This study is to evaluate Net Primary Production (NPP) using NDVI calculated by MODIS in the Nakdong river basin. This study is based on the method of using the fact that NPP is proportional to natural vegetation condition. This method is different from existing one, using remote sensed data. It is known that NPP of natural vegetation is proportional to the absorbed amount of visible light that is proportional to NDVI. Therefore, estimating NPP by using NDVI is one of the most highly useful methods. This method can be used in a wide range of areas where vegetation data can not be obtained easily or where there is not enough meterological data. This study proposes the estimating method for NPP that is based upon NDVI, which is obtained by MODIS, and verifies by comparing the NPP with empirical results.