This study was conducted to investigate the main cause of water quality deterioration during the spring season in the transition zone between the South Han River and the river-reservoir Paldang. A water quality model modified from QUAL2E (U.S.EPA) was used, and the model showed that eutrophication and algal production in the low flow season affected about 60% of the organic pollution at the downstream of the South Han River. This result means that phosphorus control is prior to external organic material management to ameliorate the deterioration of water quality in the water body.