The experiment was done on traveling at the speed of 20km/h, 60km/h and 100km/h using the performance testing mode for chassis dynamometer. The experimental method were employed to measure the waveform of secondary ignition coil and exhaust emission. In this experiment, the correlation between the secondary waveform coming from ignition coil and exhaust emission were measured in decrepit vehicle. The secondary waveform characterized by the value of effective discharge energy. The following results are obtained by analyzing the data relativity between the effective discharge energy and exhaust emission. The variation rate of effective discharge energy was largest 60km/h, 20km/h, 100km/h velocity in the ordered named. As the vehicle velocity increases, the average variation rate of CO and $NO_X$ decreases and that of HC and $CO_2$ decrease. The value of effective discharge energy, CO, $NO_X$ and fuel consumption is measured badly in case of car with failures in MAP, spark plug and good in case of car with before and after maintenance regardless of vehicle velocities. The value of effective discharge energy is to be nearly parabolic shape as vehicle velocity increases. As the value of effective discharge energy increases, the value of $NO_X$, HC and $CO_2$ decrease, the value of CO increase. The most sensible factors of exhaust emission were CO, $NO_X$, and the small variation factors were HC, $CO_2$.