Currently, there are active researches being conducted on a new combustion technology that can reduce emission quantity while enhancing vehicle performance as well as Improving fuel quality. In a gasoline engine that uses petroleum, high volatility makes it easy to jump spark ignition and prevent knocking phenomenon that occurs inside an engine. In a diesel engine that uses diesel fuel, high volatility reduces combustion residues and toxic gas and is therefore good for protecting the environment. Therefore, for fuel used in a vehicle, volatility is an important factor that influences not only engine performance but also environmental protection. This research conducted a distillation experiment using gasoline and diesel fuel for vehicles produced by domestic oil companies. The test was conducted in accordance with the method of distillation experiment described in KS M ISO3405. In addition, it used the result of analysis from the experiment to examine visual distillation characteristics of each fuel and developed a formula based on distillation temperature.