The study on PVC removal from home appliance packing materials was conducted by using triboelectrostatic separation technique. For the effective separation of the sample(PVC, PET), charge polarity and amount of each sample with various charging materials have been investigated by faraday cage. And then, charging material was selected as carrying out basic separation experiments with materials that can be possible to polarize samples. Finally, the continuos type triboelectrostatic separator was developed with selected charging material and the recovery possibility of the sample was confirmed as carrying out various separation experiments.