기관회원 [로그인]
소속기관에서 받은 아이디, 비밀번호를 입력해 주세요.
개인회원 [로그인]

비회원 구매시 입력하신 핸드폰번호를 입력해 주세요.
본인 인증 후 구매내역을 확인하실 수 있습니다.

회원가입
서지반출
CO2 adsorption characteristics of slit-pore shaped activated carbon prepared from cokes with high crystallinity
[STEP1]서지반출 형식 선택
파일형식
@
서지도구
SNS
기타
[STEP2]서지반출 정보 선택
  • 제목
  • URL
돌아가기
확인
취소
  • CO2 adsorption characteristics of slit-pore shaped activated carbon prepared from cokes with high crystallinity
저자명
Mi-Seon Park, Si-Eun Lee, Min Il Kim and Young-Seak Lee
간행물명
Carbon LettersKCI
권/호정보
2015년|16권 1호(통권59호)|pp.45-50 (6 pages)
발행정보
한국탄소학회|한국
파일정보
정기간행물|ENG|
PDF텍스트(2.06MB)
주제분야
자연과학
서지반출

영문초록

High crystallinity coke-based activated carbon (hc-AC) is prepared using a potassium hydroxide solution to adsorb carbon dioxide (CO2). The CO2 adsorption characteristics of the prepared hc-AC are investigated at different temperatures. The X-ray diffraction patterns indicate that pitch-based cokes prepared under high temperature and pressure have a high crystal structure. The textural properties of hc-AC indicate that it consists mainly of slit-like pores. Compared to other textural forms of AC that have higher pore volumes, this slit-poreshaped hc-AC exhibits higher CO2 adsorption due to the similar shape between its pores and CO2 molecules. Additionally, in these high-crystallinity cokes, the main factor affecting CO2 adsorption at lower temperature is the pore structure, whereas the presence of oxygen functional groups on the surface has a greater impact on CO2 adsorption at higher temperature.

목차

1. Introduction
2. Experimental
3. Results and Discussion
4. Conclusions
References

참고문헌 (26건)

  • Bai BC, Cho S, Yu HR, Yi KB, Kim KD, Lee YS. Effects of aminated carbon molecular sieves on breakthrough curve behavior in CO2/CH4 separation. J Ind Eng Chem, 19, 776 (2013). http://dx.doi.org/10.1016/j.jiec.2012.10.016.
  • Miyamoto M, Fujioka Y, Yogo K. Pure silica CHA type zeolite for CO2 separation using pressure swing adsorption at high pressure. J Mater Chem, 22, 20186 (2012). http://dx.doi.org/10.1039/C2JM34597H.
  • Cho S, Yu HR, Kim KD, Yi KB, Lee YS. Surface characteristics and carbon dioxide capture characteristics of oxyfluorinated carbon molecular sieves. Chem Eng J, 211-212, 89 (2012). http://dx.doi.org/10.1016/j.cej.2012.09.047.
  • Xu X, Song C, Andresen JM, Miller BG, Scaroni AW. Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for CO2 capture. Energy Fuels, 16, 1463 (2002). http://dx.doi.org/10.1021/ef020058u.
  • Siriwardane RV, Shen M-S, Fisher EP, Losch J. Adsorption of CO2 on zeolites at moderate temperatures. Energy Fuels, 19, 1153 (2005). http://dx.doi.org/10.1021/ef040059h.
  • Labus K, Gryglewicz S, Machnikowski J. Granular KOH-activated carbons from coal-based cokes and their CO2 adsorption capacity. Fuel, 118, 9 (2014). http://dx.doi.org/10.1016/j.fuel.2013.10.042.
  • Lee SG, Park KH, Shim WG, balathanigaimani MS, Moon H. Performance of electrochemical double layer capacitors using highly porous activated carbons prepared from beer lees. J Ind Eng Chem, 17, 450 (2011). http://dx.doi.org/10.1016/j.jiec.2010.10.025.
  • Adinaveen T, Kennedy LJ, Vijaya JJ, Sekaran G. Studies on structural, morphological, electrical and electrochemical properties of activated carbon prepared from sugarcane bagasse. J Ind Eng Chem, 19, 1470 (2013). http://dx.doi.org/10.1016/j.jiec.2013.01.010.
  • Jagiello J, Tolles ED. Calculation of pore size distribution of activated carbons based on density functional theory (DFT) data. In: Meunier F, ed. Fundamentals of Adsorption 6, Elsevier, New York, NY, 629 (1998).
  • Yu L, Kim KJ, Park DY, Kim MS, Kim KI, Lim YS. Preparation and characterization of pitch/cokes composite anode material for high power lithium secondary battery. Carbon Lett, 9, 210 (2008). http://dx.doi.org/10.5714/CL.2008.9.3.210.
  • Park MS, Cho S, Jeong E, Lee YS. Physico-chemical and electrochemical properties of pitch-based high crystallinity cokes used as electrode material for electric double layer capacitor. J Ind Eng Chem, in press. http://dx.doi.org/10.1016/j.jiec.2014.07.038.
  • Condon JB. Surface Area and Porosity Determinations by Physisorption: Measurements and Theory, Elsevier, Amsterdam (2006).
  • Yu HR, Cho S, Jung MJ, Lee YS. Electrochemical and structural characteristics of activated carbon-based electrodes modified via phosphoric acid. Microporous Mesoporous Mater, 172, 131 (2013). http://dx.doi.org/10.1016/j.micromeso.2013.01.018.
  • An H, Feng B, Su S. CO2 capture by electrothermal swing adsorption with activated carbon fibre materials. Int J Greenh Gas Control, 5, 16 (2011). http://dx.doi.org/10.1016/j.ijggc.2010.03.007.
  • Shafeeyan MS, Daud WMAW, Houshmand A, Shamiri A. A review on surface modification of activated carbon for carbon dioxide adsorption. J Anal Appl Pyrolysis, 89, 143 (2010). http://dx.doi.org/10.1016/j.jaap.2010.07.006.
  • Tressaud A, Durand E, Labrugère C. Surface modification of several carbon-based materials: comparison between CF4 rf plasma and direct F2-gas fluorination routes. J Fluorine Chem, 125, 1639 (2004). http://dx.doi.org/10.1016/j.jfluchem.2004.09.022.
  • Mathur RB, Gupta V, Bahl OP, Tressaud A, Flandrois S. Improvement in the mechanical properties of polyacrylonitrile (PAN)-based carbon fibers after fluorination. Synth Met, 114, 197 (2000). http://dx.doi.org/10.1016/S0379-6779(00)00251-4.
  • Cho SH, Bai BC, Yu HR, Lee YS. Carbon capture and CO2/CH4 separation technique using porous carbon materials. Appl Chem Eng, 22, 343 (2011).
  • Lee CS, Ong YL, Aroua MK, Daud WMAW. Impregnation of palm shell-based activated carbon with sterically hindered amines for CO2 adsorption. Chem Eng J, 219, 558 (2013). http://dx.doi.org/10.1016/j.cej.2012.10.064.
  • Shafeeyan MS, Daud WMAW, Houshmand A, Arami-Niya A. Ammonia modification of activated carbon to enhance carbon dioxide adsorption: effect of pre-oxidation. Appl Surf Sci, 257, 3936 (2011). http://dx.doi.org/10.1016/j.apsusc.2010.11.127.
  • Pevida C, Plaza MG, Arias B, Fermoso J, Rubiera F, Pis JJ. Surface modification of activated carbons for CO2 capture. Appl Surf Sci, 254, 7165 (2008). http://dx.doi.org/10.1016/j.apsusc.2008.05.239.
  • Plaza MG, García S, Rubiera F, Pis JJ, Pevida C. Evaluation of ammonia modified and conventionally activated biomass based carbons as CO2 adsorbents in postcombustion conditions. Sep Purif Technol, 80, 96 (2011). http://dx.doi.org/10.1016/j.seppur.2011.04.015.
  • Heidari A, Younesi H, Rashidi A, Ghoreyshi AA. Evaluation of CO2 adsorption with eucalyptus wood based activated carbon modified by ammonia solution through heat treatment. Chem Eng J, 254, 503 (2014). http://dx.doi.org/10.1016/j.cej.2014.06.004.
  • Deng S, Wei H, Chen T, Wang B, Huang J, Yu G. Superior CO2 adsorption on pine nut shell-derived activated carbons and the effective micropores at different temperatures. Chem Eng J, 253, 46 (2014). http://dx.doi.org/10.1016/j.cej.2014.04.115.
  • Torrisi A, Mellot-Draznieks C, Bell RG. Impact of ligands on CO2 adsorption in metal-organic frameworks: first principles study of the interaction of CO2 with functionalized benzenes. I. Inductive effects on the aromatic ring. J Chem Phys, 130, 194703 (2009). http://dx.doi.org/10.1063/1.3120909.
  • Torrisi A, Mellot-Draznieks C, Bell RG. Impact of ligands on CO2 adsorption in metal-organic frameworks: first principles study of the interaction of CO2 with functionalized benzenes. II. Effect of polar and acidic substituents. J Chem Phys, 132, 044705 (2010). http://dx.doi.org/10.1063/1.3276105.
구매하기 (3,000)
추천 연관논문