Due to high imperviousness rates of the roads, various pollutants originated from vehicle activities and air depositions are accumulated on the road surfaces. The washed-off pollutants can deteriorate the water quality and destroy the aqua-ecosystems with their toxicity. Usually the roads are paved with asphalt and concrete, which can affect on the pollutant concentrations with different frictional forces. Therefore, this research is performed to evaluate the influences of different pavement type on discharged concentrations of pollutant. The results shows the first flush phenomenon was occurred on both pavement types. However, peak concentrations are higher in concrete pavement areas than asphalt pavement because concrete pavement has high contact area with vehicles. The EMCs(Event Mean Concentration) also shows high values in concrete paved roads. As a result of this research, it can be concluded the pavement type is also one of the important affecting factors on pollutant emissions from the roads.