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Carbon-Based Solid Acid as an Efficient and Reusable Catalyst for the Synthesis of 1,8-Dioxodecahydroacridines Under Solvent-Free Conditions
Davoodnia. Abolghasem, Khojastehnezhad. Amir, Tavakoli-Hoseini. Niloofar 대한화학회 Bulletin of the Korean Chemical Society 6 Pages
대한화학회 Bulletin of the Korean Chemical Society 2011, Vol.32 No.7 2243-2248 (6 pages)
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Carbon-based Solid Acid Catalyzed One-pot Mannich Reaction: A Facile Synthesis of β-Amino Carbonyl Compounds
Davoodnia. Abolghasem, Tavakoli-Nishaburi. Afsaneh, Niloofar. Tavakoli-Hoseini 대한화학회 Bulletin of the Korean Chemical Society 4 Pages
대한화학회 Bulletin of the Korean Chemical Society 2011, Vol.32 No.2 635-638 (4 pages)
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Applications of carbon-based materials in solid phase micro-extraction: a review
Jian Guo, Soo-Jin Park, Long-Yue Meng, Xinghua Jin 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2017, Vol.24 2 10-17 (8 pages)
of sample preparation technology, solid phase micro-extraction (SPME) has been widely used in analytical chemistry for high extraction efficiency and convenient operation. Different materials lead to different extraction results. Among existing materials, carbon-based materials are still attracting attention from scientists due to their excellent physical and chemical properties as well as their modifiable surfaces, which could enhance the adsorption effects of SPME fiber. This review introduces... -
Microwave heating of carbon-based solid materials
Teawon Kim, Jaegeun Lee, Kun Hong Lee 한국탄소학회 Carbon Letters 10 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.1 2 15-24 (10 pages)
of carbon-based materials has been mainly limited to liquid solutions. However, more rapid and efficient heating is possible in electron-rich solid materials, because the target materials absorb the energy of microwaves effectively and exclusively. Carbon-based solid materials are suitable for microwave- heating due to the delocalized pi electrons from sp2-hybridized carbon networks. In this perspective review, research on the microwave heating of carbon-based solid materials is extensively... -
Superhydrophobic carbon-based materials: a review of synthesis, structure, and applications
Long-Yue Meng, Soo-Jin Park 한국탄소학회 Carbon Letters 16 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 5 89-104 (16 pages)
Materials with appropriate surface roughness and low surface energy can form superhydrophobic surfaces, displaying water contact angles greater than 150°. Superhydrophobic carbon-based materials are particularly interesting due to their exceptional physicochemical properties. This review discusses the various techniques used to produce superhydrophobic carbon-based materials such as carbon fibers, carbon nanotubes, graphene, amorphous carbons, etc. Recent advances in emerging fields such as... -
Morphologies and surface properties of cellulose-based activated carbon nanoplates
Seulbee Lee, Min Eui Lee, Min Yeong Song, Se Youn Cho, Young Soo Yun, Hyoung-Joon Jin 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2016, Vol.20 5 32-38 (7 pages)
In this study, cellulose nanoplates (CNPs) were fabricated using cellulose nanocrystals obtained from commercial microcrystalline cellulose (MCC). Their pyrolysis behavior and the characteristics of the product carbonaceous materials were investigated. CNPs showed a relatively high char yield when compared with MCC due to sulfate functional groups introduced during the manufacturing process. In addition, pyrolyzed CNPs (CCNPs) showed more effective chemical activation behavior compared with... -
One-step synthesis of dual-transition metal substitution on ionic liquid based N-doped mesoporous carbon for oxygen reduction reaction
Ulziidelger Byambasuren, Yukwon Jeon, Dorjgotov Altansukh, Yunseong Ji, Yong-Gun Shul 한국탄소학회 Carbon Letters 12 Pages
한국탄소학회 Carbon Letters 2016, Vol.17 No.1 8 53-64 (12 pages)
Nitrogen (N)-doped ordered mesoporous carbons (OMCs) with a dual transition metal system were synthesized as non-Pt catalysts for the ORR. The highly nitrogen doped OMCs were prepared by the precursor of ionic liquid (3-methyl-1-butylpyridine dicyanamide) for N/C species and a mesoporous silica template for the physical structure. Mostly, N-doped carbons are promoted by a single transition metal to improve catalytic activity for ORR in PEMFCs. In this study, our N-doped mesoporous carbons were... -
Preparation of novolac-type phenol-based activated carbon with a hierarchical pore structure and its electric double-layer capacitor performance
Dayoung Lee, Jin-Young Jung, Mi-Seon Park, Young-Seak Lee 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.3 6 192-197 (6 pages)
A hierarchical pore structured novolac-type phenol based-activated carbon with micropores and mesopores was fabricated. Physical activation using a sacrificial silicon dioxide (SiO2) template and chemical activation using potassium hydroxide (KOH) were employed to prepare these materials. The morphology of the well-developed pore structure was characterized using field-emission scanning electron microscopy. The novolac-type phenol-based activated carbon retained hierarchical pores (micropores... -
Recent Advances in Carbon-Nanotube-Based Epoxy Composites
Fan-LongJin, Soo-JinPark 한국탄소학회 Carbon Letters 13 Pages
한국탄소학회 Carbon Letters 2013, Vol.14 No.1 1 1-13 (13 pages)
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Kinetic and multi-parameter isotherm studies of picric acid removal from aqueous solutions by carboxylated multi-walled carbon nanotubes in the presence and absence of ultrasound
Soheila Gholitabar, Hasan Tahermansouri 한국탄소학회 Carbon Letters 11 Pages
한국탄소학회 Carbon Letters 2017, Vol.22 2 14-24 (11 pages)
Carboxylated multi-wall carbon nanotubes (MWCNTs-COOH) have been used as efficient adsorbents for the removal of picric acid from aqueous solutions under stirring and ultrasound conditions. Batch experiments were conducted to study the influence of the different parameters such as pH, amount of adsorbents, contact time and concentration of picric acid on the adsorption process. The kinetic data were fitted with pseudo-first order, pseudo-secondorder, Elovich and intra-particle diffusion models.... -
Extraction and characterization of lignin from black liquor and preparation of biomass-based activated carbon therefrom
Daeyeon Kim, Jinsil Cheon, Jeonghoon Kim, Daekyun Hwang, Ikpyo Hong, Oh Hyeong Kwon, Won Ho Park, Donghwan Cho 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2017, Vol.22 14 81-88 (8 pages)
In the present study, biomass-based lignin was extracted from industrial waste black liquor and the extracted lignin was characterized by means of attenuated total reflectance- Fourier transform infrared spectroscopy and 1H-nuclear magnetic resonance spectroscopy. The extracted lignin was carbonized at different temperatures and then activated with steam at 850oC. The extracted lignin in powder state was transformed into a bulky carbonized lignin due to possible fusion between the lignin... -
Biocomposite membranes based on poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and multiwall carbon nanotubes for gas separation
Mongyoung Huh, Hye Min Lee, Young Soo Park, Seok Il Yun 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2017, Vol.21 17 116-121 (6 pages)
The development of gas separation membranes is currently an active research area because of the rapidly increasing interest in carbon dioxide capture and hydrogen recovery, which are two of the most important solutions for problems related to energy and the environment [1-4]. Polymer membranes show selectivity in the separation of gases due to differences in the permeability of individual gases through the polymer film [3,4]. Even though advantageous in terms of low cost, the segmental... -
Pitch-based carbon fibers from coal tar or petroleum residue under the same processing condition
Jiyoung Kim, Ui-Su Im, Byungrok Lee, Dong-Hyun Peck, Seong-Ho Yoon, Doo-Hwan Jung 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2016, Vol.19 9 72-78 (7 pages)
and carbon fibers were successfully prepared from petroleum or coal pyrolysis residues. After pyrolysis fuel oil (PFO), slurry oil, and coal tar were simply filtered to eliminate the solid impurities, the characteristics of the raw materials were evaluated by elemental analysis, 13C nuclear magnetic resonance spectrometer, matrix-assisted laser desorption/ionization time-of-flight mass spectrometer (MALDI-TOF-MS), and so on. Spinnable pitches were prepared for melt-spinning carbon fiber through... -
Cellulose-based carbon fibers prepared using electron-beam stabilization
Min Il Kim, Mi-Seon Park, Young-Seak Lee 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2016, Vol.18 9 56-61 (6 pages)
Cellulose fibers were stabilized by treatment with an electron-beam (E-beam). The properties of the stabilized fibers were analyzed by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis. The E-beam-stabilized cellulose fibers were carbonized in N₂ gas at 800°C for 1 h, and their carbonization yields were measured. The structure of the cellulose fibers was determined to have changed to hemicellulose and... -
Advances in liquid crystalline nano-carbon materials: preparation of nano-carbon based lyotropic liquid crystal and their fabrication of nano-carbon fibers with liquid crystalline spinning
Yong-Mun Choi, in Jung Jun Yeon, Hwang Seung Min, Kim Hyeonsu Jeong, Bon-Cheol Ku, Munju Goh 한국탄소학회 Carbon Letters 10 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.4 1 223-232 (10 pages)
This review presents current progress in the preparation methods of liquid crystalline nanocarbon materials and the liquid crystalline spinning method for producing nano-carbon fibers. In particular, we focus on the fabrication of liquid crystalline carbon nanotubes by spinning from superacids, and the continuous production of macroscopic fiber from liquid crystalline graphene oxide. -
Effects of cross-linking methods for polyethylene-based carbon fibers: review
Kwan-Woo Kim, Hye-Min Lee, Jeong-Hun An, Byoung-Suhk Kim, Byung-Gak Min, Shin-Jae Kang, Kay-Hyeok An, Byung-Joo Kim 한국탄소학회 Carbon Letters 24 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 2 147-170 (24 pages)
and the use of CFRP has been impeded by the high cost of CF in various applications. This paper presents an overview of research related to the fabrication of low cost CF using polyethylene (PE) control technology, and identifies areas requiring additional research and development. It critically reviews the results of cross-linked PE control technology studies, and the development of promising control technologies, including acid, peroxide, radiation and silane cross-linking methods. -
Optical sensitivity of DNA-dispersed single-walled carbon nanotubes within cement composites under mechanical load
Jin Hee Kim, Inkyu Rhee, Yong Chae Jung, Sumin Ha, Yoong Ahm Kim 한국탄소학회 Carbon Letters 7 Pages
한국탄소학회 Carbon Letters 2017, Vol.24 12 90-96 (7 pages)
mechanical load. Deoxyribonucleic acid (DNA) was selected as the dispersing agent to achieve a homogeneous dispersion of SWCNTs in an aqueous solution, and the dispersion state of the SWCNTs were characterized using various optical tools. It was found that the addition of a large amount of DNA prohibited the structural evolution of calcium hydroxide and calcium silicate hydrate. Based on the in-situ Raman and X-ray diffraction studies, it was evident that hydrophilic functional groups within the... -
Improvement of gas sensing properties of carbon nanofibers based on polyacrylonitrile and pitch by steam activation
Jeongsik Kim, Hyung-Il Kim, Jumi Yun 한국탄소학회 Carbon Letters 5 Pages
한국탄소학회 Carbon Letters 2017, Vol.24 5 36-40 (5 pages)
Polyacrylonitrile/pitch nanofibers were prepared by electrospinning as a precursor for a gas sensor material. Pitch nanofibers were properly fabricated by incorporating polyacrylonitrile as an electrospinning supplement component. Polyacrylonitrile/pitch nanofibers were activated with steam at various temperatures followed by subsequent carbonization to make carbon nanofibers with a highly conductive graphitic structure. Steam activation was effective in facilitating gas adsorption onto the... -
Effect of the surface modification using MWCNTs with different L/D by two different methods of deposition on the IFSS of single carbon fiber-epoxy resin composite
Minerva L. Herrera-Sosa, Alex Valadez-Gonz?lez, Humberto V?zquez-Torres, Pierre G. Mani-Gonz?lez, Pedro J. Herrera-Franco 한국탄소학회 Carbon Letters 10 Pages
한국탄소학회 Carbon Letters 2017, Vol.24 3 18-27 (10 pages)
Multiwall carbon nanotubes (MWCNT) with two different (L/D) aspect ratios (7±2 μm/140±30 nm and 0.5?2 μm/8?15 nm) were surface treated using nitric acid (HNO3) and polyethyleneimine (PEI) prior to their deposition on carbon fibers (CF). Before the hierarchical reinforcement with CF-MWCNT, the CFs were treated with 3-glycidoxypropyltrimethoxysilane, a coupling agent (Z6040) and with poly(amidoamine) (PAMAM) a dendrimer containing an ethylenediamine core and amine surface groups. The MWCNT... -
Preparation and characterization of carbon fiber-reinforced thermosetting composites: a review
Fan-Long Jin, Soo-Jin Park 한국탄소학회 Carbon Letters 11 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.2 1 67-77 (11 pages)
Carbon fibers (CFs) have a unique combination of properties which allow them to be widely used as reinforcing materials in advanced polymer composites. The mechanical properties of CF-reinforced polymer composites are governed mainly by the quality of interfacial adhesion between the CFs and the polymer matrix. Surface treatments of CFs are generally carried out to introduce chemical functional groups on the fiber surfaces, which provide the ability to control the surface characteristics of CFs.... -
Double-walled carbon nanotubes: synthesis, structural characterization, and application
Yoong Ahm Kim, Kap-Seung Yang, Hiroyuki Muramatsu, Takuya Hayashi, Morinobu Endo, Mauricio Terrones, Mildred S. Dresselhaus 한국탄소학회 Carbon Letters 12 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.2 4 77-88 (12 pages)
Double walled carbon nanotubes (DWCNTs) are considered an ideal model for studying the coupling interactions between different concentric shells in multi-walled CNTs. Due to their intrinsic coaxial structures they are mechanically, thermally, and structurally more stable than single walled CNTs. Geometrically, owing to the buffer-like function of the outer tubes in DWCNTs, the inner tubes exhibit exciting transport and optical properties that lend them promise in the fabrication of field-effect... -
Simultaneous HPLC Analysis of Arachidonic Acid Metabolites in Biological Samples with Simple Solid Phase Extraction
Hyung-GunKim, Young-NaHuh, Kun-SukPark 대한생리학회-대한약리학회 The Korean Journal of Physiology & Pharmacology 8 Pages
대한생리학회-대한약리학회 The Korean Journal of Physiology & Pharmacology 1998, Vol.2 No.6 15 779-786 (8 pages)
α, and thromboxane B2 (TXB2)} and lipid peroxidation product, isoprostanes, of arachidonic acid were monitored by one isocratic HPLC system at 195 nm wavelength. The lipoxygenase products {leukotriene(LT)B4, LTC4, LTD4, and 5-hydroxyeicosatetraenoic acid (5-HETE), 12-HETE, 15-HETE} were measured by another isocratic HPLC system at 280 nm for LTs and 235 nm for HETEs. This method provides a simple and reliable way to extract and assess quantitatively the final arachidonic acid metabolites. -
Capacitance behaviors of conducting polymer-coated graphene nanosheets composite electrodes containing multi-walled carbon nanotubes as additives
Hoe-Seung Kim, Yongju Jung, Seok Kim 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2017, Vol.23 9 63-68 (6 pages)
Global warming is rapidly becoming a major concern as a result of the continuing emissions of greenhouse gases generated by the combustion of fossil fuels. To resolve this problem, various studies on efficient energy storage devices have been undertaken. Electronic technologies are increasingly used in electronic products and systems, and they require effective energy storage [1,2]. Supercapacitors are energy storage devices with high power density and long cycle life, and have been spotlighted... -
Electrochemical determination of chloramphenicol using a glassy carbon electrode modified with dendrite-like Fe₃O₄ nanoparticles
Krishnan Giribabu, Sung-Chan Jang, Yuvaraj Haldorai, Muruganantham Rethinasabapathy, Seo Yeong Oh, Arunkumar Rengaraj, Young-Kyu Han 한국탄소학회 Carbon Letters 10 Pages
한국탄소학회 Carbon Letters 2017, Vol.23 6 38-47 (10 pages)
In this study, magnetite (Fe3O4) nanoparticles were electrochemically synthesized in an aqueous electrolyte at a given potential of -1.3 V for 180 s. Scanning electron microscopy revealed that dendrite-like Fe3O4 nanoparticles with a mean size of < 80 nm were electrodeposited on a glassy carbon electrode (GCE). The Fe3O4/GCE was utilized for sensing chloramphenicol (CAP) by cyclic voltammetry and square wave voltammetry. A reduction peak of CAP at the Fe3O4/GCE was observed at 0.62 V, whereas... -
Nitrogen-doped carbon nanosheets from polyurethane foams and removal of Cr(VI)
Jiaqi Duan, Baohua Zhang, Huailin Fan, Wenzhong Shen, Shijie Qu 한국탄소학회 Carbon Letters 10 Pages
한국탄소학회 Carbon Letters 2017, Vol.22 7 60-69 (10 pages)
hydrothermal carbonization following ZnCl2 chemical activation. Scanning electron microscopy, thermogravimetric analysis, Fourier transform infrared spectroscopy, solid state 13C nuclear magnetic resonance (NMR) spectra and X-ray photoelectron spectroscopy were used to characterize the nitrogen-doped carbon nanosheet structure and composition. The removal of Cr(VI) by the N-doped carbon nanosheets was investigated. The results showed that the maximum removal capacity for chromium of 188 mg/g was... -
Synthesis and characterization of carbon doped TiO₂ photocatalysts supported on stainless steel mesh by sol-gel method
JO. Tijani, OO. Fatoba, TC. Totito, WD. Roos, LF. Petrik 한국탄소학회 Carbon Letters 12 Pages
한국탄소학회 Carbon Letters 2017, Vol.22 6 48-59 (12 pages)
This study synthesized pure anatase carbon doped TiO₂ photocatalysts supported on a stainless steel mesh using a sol-gel solution of 8% polyacrylonitrile (PAN)/dimethylformamide (DMF)/TiCl₄. The influence of the pyrolysis temperature and holding time on the morphological characteristics, particle sizes and surface area of the prepared catalyst was investigated. The prepared catalysts were characterized by several analytical methods: high resolution scanning electron microscopy (HRSEM), energy... -
Synthesize multi-walled carbon nanotubes via catalytic chemical vapour deposition method on Fe-Ni bimetallic catalyst supported on kaolin
Aliyu A, Abdulkareem AS, Kovo AS, Abubakre OK, Tijani JO, Kariim I 한국탄소학회 Carbon Letters 18 Pages
한국탄소학회 Carbon Letters 2017, Vol.21 5 33-50 (18 pages)
In this study, Fe-Ni bimetallic catalyst supported on kaolin is prepared by a wet impregnation method. The effects of mass of kaolin support, pre-calcination time, pre-calcination temperature and stirring speed on catalyst yields are examined. Then, the optimal supported Fe-Ni catalyst is utilised to produce multi-walled carbon nanotubes (MWCNTs) using catalytic chemical vapour deposition (CCVD) method. The catalysts and MWCNTs prepared using the optimal conditions are characterized using high... -
Effects of electrochemical oxidation of carbon fibers on interfacial shear strength using a micro-bond method
Dong-Kyu Kim, Kay-Hyeok An, Yun Hyuk Bang, Lee-Ku Kwac, Sang-Yub Oh, Byung-Joo Kim 한국탄소학회 Carbon Letters 8 Pages
한국탄소학회 Carbon Letters 2016, Vol.19 4 32-39 (8 pages)
In this work, we studied the effects of electrochemical oxidation treatments of carbon fibers (CFs) on interfacial adhesion between CF and epoxy resin with various current densities. The surface morphologies and properties of the CFs before and after electrochemical-oxidation-treatment were characterized using field emission scanning electron microscopy, atomic force microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and single-fiber contact angle. The... -
Mechanical interfacial adhesion of carbon fibers-reinforced polarized-polypropylene matrix composites: effects of silane coupling agents
Woong-Ki Choi, Hyun-Il Kim, Shin-Jae Kang, Young Sil Lee, Jong Hun Han, Byung-Joo Kim 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2016, Vol.17 No.1 12 79-84 (6 pages)
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Flexural properties, interlaminar shear strength and morphology of phenolic matrix composites reinforced with xGnP-coated carbon fibers
Jong Kyoo Park, Jae Yeol Lee, Lawrence T. Drzal, Donghwan Cho 한국탄소학회 Carbon Letters 6 Pages
한국탄소학회 Carbon Letters 2016, Vol.17 No.1 5 33-38 (6 pages)
In the present study, exfoliated graphite nanoplatelets (xGnP) with different particle sizes were coated onto polyacrylonitrile-based carbon fibers by a direct coating method. The flexural properties, interlaminar shear strength, and the morphology of the xGnP-coated carbon fiber/phenolic matrix composites were investigated in terms of their longitudinal flexural strength and modulus, interlaminar shear strength, and by optical and scanning electron microscopic observations. The results were... -
Micro-sized carbon with dimple patterns prepared using an electro-spray method
Mi-Seon Park, Young-Seak Lee 한국탄소학회 Carbon Letters 4 Pages
한국탄소학회 Carbon Letters 2015, Vol.16 No.3 9 215-218 (4 pages)
Carbon micro particles with dimple patterns were produced by electro-spraying a solution of pitch in tetrahydrofuran. Particle formation depended on separation in an electrical field and volatilization of the solvent. More than 80% of the obtained carbon exhibited an average particle size of less than 50 μm. X-ray diffraction analysis suggests that the carbon with dimple patterns has increased crystallinity after heat treatment. -
Carbon-allotropes: synthesis methods, applications and future perspectives
P. S. Karthik, A. L. Himaja and Surya Prakash Singh 한국탄소학회 Carbon Letters 19 Pages
한국탄소학회 Carbon Letters 2014, Vol.15 No.4 1 219-237 (19 pages)
The element carbon has been used as a source of energy for the past few hundred years, and now in this era of technology, carbon has played a significant and very prominent role in almost all fields of science and technology. So as an honour to this marvellous element, we humans should know about its various forms of existence. In this review article, we shed light on all possible carbon-allotropes; similarities in their synthesis techniques and the starting materials; their wide range of... -
Carbon Doping of TiO2 for Visible Light Photo Catalysis - A review
K. Palanivelu, Ji Sun Im, Young-Seak Lee 한국탄소학회 Carbon Letters 11 Pages
한국탄소학회 Carbon Letters 2007, Vol.8 No.3 6 214-224 (11 pages)
