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A Study of Nonstoichiometric Empirical Formulas for Semiconductive Metal Oxides
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  • A Study of Nonstoichiometric Empirical Formulas for Semiconductive Metal Oxides
  • A Study of Nonstoichiometric Empirical Formulas for Semiconductive Metal Oxides
저자명
Kim. Kyung-Sun,Lee. Kwan-Hee,Cho. Ung-In,Choi. Jae-Shi
간행물명
Bulletin of the Korean Chemical Society
권/호정보
1986년|7권 1호|pp.29-35 (7 pages)
발행정보
대한화학회
파일정보
정기간행물|ENG|
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기타
이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

An empirical formula for semiconductive metal oxides is proposed relating nonstoichiometric value x to a temperature or an oxygen partial pressure such that experimental data can be represented more accurately by the formula than by the well-known Arrhenius-type equation. The proposed empirical formula is log x = A + $B{cdot}1000/T;+;C{cdot}$exp$(-D{cdot}1000/T)$ for a temperature dependence and $log;{ imes};=a;+b{cdot}log;Po_2;+;c{cdot}$exp$(-d{cdot}log;Po_2)$ for an oxygen partial pressure dependence. The A, B, C, D and a, b, c, d are parameters which are evaluated by means of a best-fitting method to experimental data. Subsequently, this empirical formula has been applied to the n-type metal oxides of $Zn_{1+x}O,; Cd_{1+x}O,;and;PrO_{1.8003-x}$, and the p-type metal oxides of $CoO_{1+x},; FeO_{1+x},;and;Cu_2O_{1+x}$. It gives a very good agreement with the experimental data through the best-fitted parameters within 6% of relative error. It is also possible to explain approximately qualitative characters of the parameters A, B, C, D and a, b, c, d from theoretical bases.