- Ferricyanide-Sensing Electrodes
- Ferricyanide-Sensing Electrodes
- ㆍ 저자명
- Ihn. Gwon-Shik
- ㆍ 간행물명
- Bulletin of the Korean Chemical Society
- ㆍ 권/호정보
- 1986년|7권 1호|pp.36-38 (3 pages)
- ㆍ 발행정보
- 대한화학회
- ㆍ 파일정보
- 정기간행물|ENG| PDF텍스트
- ㆍ 주제분야
- 기타
The Ferricyanide-sensing electrodes were prepared with $Ag_2S;and;Ag_3Fe(CN)_6$ (mole ratio 3:1-7:1). The 5:1 $(Ag_2S:Ag_3Fe(CN)_6)$ composition is superior to others in terms of potentiometric response, rapidity of response and reproducibility. Testing was done over the concentration range $10^{-1}M{sim}10^{-6}M; Fe(CN)_6^{3-}$ at pH 6.8 with constant ionic strength. The concentration-potential curve was linear and coincided with the Nernstian slope (19.7 mV/decade). Interfering ions were $I^-,;Br^-,; SCN^-;and;Fe(CN)_6^{4-}$ and the life time of this electrode was 3 weeks. This electrode could be used as the indicator electrode for measuring the ferricyanide and ferrocyanide.