We have developed XeCl laser pumped double-resonator Dye laser and two-stage amplifier system, and generated simultaneously of alternatively two wavelengths suitable in DIAL system. The developed double-resonator is composed of 1st and 2nd diffraction orders on light incidence angle in grazing-incidence grating method with 1200 g/mm. We have obtained spectral linewidth below 10 pm and the total efficiency dependent on pump energy over 6%. The tuning ranges dependent on 1st and 2nd diffraction orders are 434~470 nm and 436~468 nm, respectively. The amplification gain and rine-450 dye laser by using the double-resonator laser system and measured the distribution of $NO_2$ concentration over Suwon as the result of transmission of laser output of 6 mJ in this DIAL system. Consequently, we have confirmed that the developed dye laser system is very useful as the tunable source for DIAL.