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NiO-YSZ 복합전도체의 전기적 특성
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  • NiO-YSZ 복합전도체의 전기적 특성
저자명
박영민,최경만
간행물명
요업학회지
권/호정보
1996년|33권 12호|pp.1403-1413 (11 pages)
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한국세라믹학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The electrical properties of NiO-YSZ composites were investigated by the measurement of a. c impedance electromotive force of galvanic cell and oxygen partial pressure dependence of electrical conductivity between 23$0^{circ}C$ and 100$0^{circ}C$. Samples of 19 compositions were sintered at 1$600^{circ}C$ for 4 h from NiO-YSZ powders made by solid state reaction. No other phase except NiO and YSZ was discovered by XRD and the solubility of NiO in YSZ was less than 10 mol% and that of YSZ in NiO was less than 1 mol% The large variation of the electrical conductivity with composition at 30$0^{circ}C$ decreased with increasing temperature. When x in xNiO-(1-x)YSZ was equal to or less than 0.4, electrical conduction was mostly dependent on ionic charge carriers of YSZ and when x was equal to or greater than 0.8 the conduction was mostly dependent on electron holes of NiO Mixed conduction was observed for 0.4<x<0.8