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$H_2$, $N_2$ 희석기체에 따른 화학증착 탄화규소의 성장 거동
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  • $H_2$, $N_2$ 희석기체에 따른 화학증착 탄화규소의 성장 거동
저자명
이영진,왕채현,최두진,박지연,홍계원
간행물명
요업학회지
권/호정보
1998년|35권 7호|pp.764-774 (11 pages)
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한국세라믹학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Silicon carbide films have been grown onto graphite substrates by low pressure chemical vapor deposition using MTS($CH_3SiCl_3$) as a source and $H_2$ or $N_2$ as a diluent gas. The experiments were performed at a fixed condition such as a flow rate of 100 sccm for each MTS and carrier gas a flow rate of 300 sccm for diluent gas addition and a total pressure of 5 torr. The effect of temperature ranged from $900^{circ}C$ to $1350^{circ}C$ and the alteration of diluent gas species on the growth rate and structure of deposits has been studied. The experimental results showed that the deposition rate increased with increasing deposition temperature irrespective of diluent gases. At both high temperature above $1300^{circ}C$ and low temperature below $1050^{circ}C$ regions the deposition rate of $N_2$ addition is faster than that of $H_2$ one but at $1100{leq}T_{dep}{leq}1250^{circ}C$ middle temperature range the opposite result obtained. It seems that these differences of deposition rate might result from boundary layer thickness and the supersaturation variations at each deposition temperature. Texture of (111), (220) and (311) planes of $eta$-SiC was maintained above $1250^{circ}C$ for $N_2$ addition whereas (111) plane was preferably orientated above $1150^{circ}C$ for $H_2$ addition. In case of $N_2$ addition $alpha$-SiC phase was observed with temperature increase. Surface morphology of SiC films were gradually changed from smooth structure to rough one with temperature increase for both diluent gas additions.